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Photo-induced reversible modification of the Curie-Weiss temperature in paramagnetic gadolinium compounds
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science and Engineering, Solid State Physics. Uppsala Univ, Dept Mat Sci & Engn, Lagerhyddsvagen 1, S-75237 Uppsala, Sweden..ORCID iD: 0000-0003-2917-8569
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science and Engineering, Solid State Physics.ORCID iD: 0000-0002-3049-6831
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science and Engineering, Solid State Physics.ORCID iD: 0000-0003-0296-5247
2024 (English)In: Solid State Communications, ISSN 0038-1098, E-ISSN 1879-2766, Vol. 378, article id 115419Article in journal (Refereed) Published
Abstract [en]

Gadolinium oxyhydride GdHO is a photochromic material that darkens under illumination and bleaches back by thermal relaxation. As an inorganic photochromic material that can be easily deposited by magnetron sputtering, GdHO has very interesting potential applications as a functional material, specially for smart glazing applications. However, the underlying reasons behind the photochromic mechanism - which can be instrumental for the correct optimisation of GdHO for different applications - are not completely understood. In this paper, we rely on the well-established magnetic properties of Gd3+ to shed light on this matter. GdHO thin films present paramagnetic behaviour similar to other Gd3+ compounds such as Gd2O3. Illumination of the films result in a reversible increase of the Curie-Weiss temperature pointing to Ruderman-Kittel-Kasuya-Yosida RKKY interactions, which is consistent with the resistivity decrease observed in the photodarkened films.

Place, publisher, year, edition, pages
Elsevier, 2024. Vol. 378, article id 115419
Keywords [en]
Oxyhydrides, Photochromism, RKKY
National Category
Condensed Matter Physics Materials Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-522889DOI: 10.1016/j.ssc.2023.115419ISI: 001150127700001OAI: oai:DiVA.org:uu-522889DiVA, id: diva2:1836908
Funder
Swedish Energy Agency, P2022-00859Available from: 2024-02-12 Created: 2024-02-12 Last updated: 2024-02-12Bibliographically approved

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Montero Amenedo, JoséSvedlindh, PeterÖsterlund, Lars

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