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Fabrication of mechanically robust nanoporous ZrSiO4 ceramics at low temperature with a low doping level of Mn dopant
Cent South Univ, Sch Mat Sci & Engn, Changsha, Peoples R China..
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science and Engineering, Applied Material Science.ORCID iD: 0009-0005-3234-5649
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science and Engineering, Microsystems Technology.ORCID iD: 0000-0001-7715-3142
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science and Engineering, Applied Material Science.ORCID iD: 0000-0001-9529-650X
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2024 (English)In: International Journal of Applied Ceramic Technology, ISSN 1546-542X, E-ISSN 1744-7402, Vol. 21, no 3, p. 1954-1964Article in journal (Refereed) Published
Abstract [en]

Zircon (ZrSiO4) ceramics have been widely used in many fields due to their excellent physical and chemical properties. However, ZrSiO4 ceramics typically possess moderately low mechanical properties, which hinders their wider application. Meanwhile, elevated temperatures (similar to 1500 degrees C) are required to obtain high-purity synthetic ZrSiO4 ceramics, which is time- and energy-consuming. In the present study, we prepared mechanically robust ZrSiO4 ceramics at low temperature (similar to 1170 degrees C) with a low doping level of Mn dopant (<2 mol%). The ZrSiO4 ceramic processed by hot isostatic pressing with .5 mol% Mn dopant achieved the highest flexural strength (512 MPa), elastic modulus (341 GPa), and nanohardness (20.8 GPa). These values are significantly higher than conventional ZrSiO4 ceramics. The strengthening mechanisms of the prepared ZrSiO4 ceramics were attributed to the formation of homogeneously-distributed nanopores due to incomplete densification and submicron ZrSiO4 grains (similar to 300 nm). The nanopores avoided stress concentration and deflected microcracks during loading, and the submicron ZrSiO4 grains endowed the ZrSiO4 ceramics with grain refinement strengthening. The results reported in this study would offer guidance to fabricate mechanically robust ZrSiO4 ceramics at low temperatures with a low doping level of dopant.

Place, publisher, year, edition, pages
John Wiley & Sons, 2024. Vol. 21, no 3, p. 1954-1964
Keywords [en]
mechanical properties, Mn doping, nanoporous, ZrO2-SiO2, ZrSiO4
National Category
Materials Chemistry Ceramics and Powder Metallurgical Materials
Identifiers
URN: urn:nbn:se:uu:diva-528434DOI: 10.1111/ijac.14652ISI: 001135511100001OAI: oai:DiVA.org:uu-528434DiVA, id: diva2:1859728
Funder
Swedish Research CouncilAvailable from: 2024-05-22 Created: 2024-05-22 Last updated: 2025-02-09Bibliographically approved

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Zhou, HuasiKlintberg, LenaEngqvist, HåkanXia, Wei

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