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The micro-structure of lactose powder compacts studied by small-angle and ultra small-angle X-ray scattering
Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Medicinal Chemistry, Pharmaceutical physical chemistry. Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Pharmaceutical Biosciences.ORCID iD: 0000-0002-0080-3714
Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Pharmaceutical Biosciences. SweDeliver, Uppsala, Sweden..ORCID iD: 0000-0003-4006-2241
Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Pharmaceutical Biosciences. SweDeliver, Uppsala, Sweden..
Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Pharmaceutical Biosciences. SweDeliver, Uppsala, Sweden..ORCID iD: 0000-0003-4013-9704
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2025 (English)In: Powder Technology, ISSN 0032-5910, E-ISSN 1873-328X, Vol. 460, article id 121090Article in journal (Refereed) Published
Abstract [en]

The objective was to derive indications of the microstructure of lactose powder compacts was studied by smallangle and ultra small-angle X-ray scattering experiments (SAXS/USAXS). Measurements were performed on a series of lactose powder compacts formed at four different pressures in the interval 300-1000 MPa. Porod analyses of the 1-D scattering profiles, i.e. intensity vs. magnitude of scattering vector (q), enabled accurate determinations of the specific surface area. From these, the interparticle contact area was estimated and compared to the compact tensile strength. Measures of the volume fraction and sizes of the voids were obtained from a fit of a model of polydisperse cylindrical pores. These were found to be approximately disc-shaped, with one dimension significantly smaller than the other two. The scattering data were consistent with an isotropic distribution of pores. The void volume fractions, void sizes and specific surface areas showed anti-correlating trends with the pressure applied.

Place, publisher, year, edition, pages
Elsevier, 2025. Vol. 460, article id 121090
Keywords [en]
SAXS, Lactose, Powder compacts, Porosity, Pore size and shape, Contact area, Tablet strength
National Category
Basic Medicine
Identifiers
URN: urn:nbn:se:uu:diva-557736DOI: 10.1016/j.powtec.2025.121090ISI: 001488997000001Scopus ID: 2-s2.0-105004187980OAI: oai:DiVA.org:uu-557736DiVA, id: diva2:1963382
Funder
EU, Horizon 2020, 654000Available from: 2025-06-03 Created: 2025-06-03 Last updated: 2025-06-03Bibliographically approved

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Gråsjö, JohanPersson, Ann-SofieAlderborn, GöranFrenning, GöranHansson, PerRennie, Adrian R.

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Gråsjö, JohanPersson, Ann-SofieAlderborn, GöranFrenning, GöranHansson, PerRennie, Adrian R.
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Pharmaceutical physical chemistryDepartment of Pharmaceutical BiosciencesMacromolecular Chemistry
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