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Design of thermal hysteresis in nonstoichiometric Fe2P-type alloys with giant magnetocaloric effect
Tech Univ Darmstadt, Inst Mat Sci, D-64287 Darmstadt, Germany..
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.ORCID iD: 0000-0002-0096-4366
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.ORCID iD: 0000-0003-0336-2560
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Materials Theory. China Univ Geosci, Fac Mat Sci & Chem, Wuhan 430074, Peoples R China..ORCID iD: 0000-0003-4165-6690
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2025 (English)In: Physical Review B, ISSN 2469-9950, E-ISSN 2469-9969, Vol. 111, no 22, article id 224401Article in journal (Refereed) Published
Abstract [en]

The nonstoichiometric Fe2P-type FeMn(1-x)Vx(P0.5Si0.5)1-x alloys (x = 0, 0.01, 0.02, and 0.03) have been investigated as potential candidates for magnetic refrigeration near room temperature. The magnetic ordering temperature decreases with increasing FeV concentration x, which can be ascribed to decreased ferromagnetic coupling strength between the magnetic atoms. The strong magnetoelastic coupling in these alloys results in large values of the isothermal entropy change (ΔSM); 15.7 J/(kg K), at 2 T magnetic field for the x = 0 alloy. ΔSM decreases with increasing x. Results from Mössbauer spectroscopy reveal that the average hyperfine field (in the ferromagnetic state) and average center shift (in the paramagnetic state) have the same decreasing trend as ΔSM. The thermal hysteresis (ΔThyst) of the magnetic phase transition decreases with increasing x, while the mechanical stability of the alloys improves due to the reduced lattice volume change across the magnetoelastic phase transition. The adiabatic temperature change ΔTad, which highly depends on ΔThyst, is 1.7 K at 1.9 T applied field for the x = 0.02 alloy.

Place, publisher, year, edition, pages
American Physical Society, 2025. Vol. 111, no 22, article id 224401
National Category
Condensed Matter Physics Metallurgy and Metallic Materials
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URN: urn:nbn:se:uu:diva-562195DOI: 10.1103/PhysRevB.111.224401ISI: 001511184900010OAI: oai:DiVA.org:uu-562195DiVA, id: diva2:1981055
Funder
Swedish Foundation for Strategic Research, EM-16-0039StandUpeSSENCE - An eScience CollaborationÅForsk (Ångpanneföreningen's Foundation for Research and Development), 22-378Available from: 2025-07-03 Created: 2025-07-03 Last updated: 2025-07-03Bibliographically approved

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Clulow, RebeccaCedervall, JohanHuang, ShuoEricsson, ToreHäggström, LennartSkini, RidhaShtender, VitaliiEriksson, OlleSahlberg, MartinSvedlindh, Peter

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Clulow, RebeccaCedervall, JohanHuang, ShuoEricsson, ToreHäggström, LennartSkini, RidhaShtender, VitaliiEriksson, OlleSahlberg, MartinSvedlindh, Peter
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