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Electrocatalytic Hydrogen Generation from Seawater at Neutral pH on a Corrosion-Resistant MoO3/Ti-Felt Electrode
Department of Chemistry, Stockholm University, Stockholm SE-106 91, Sweden.
Department of Chemistry, Stockholm University, Stockholm SE-106 91, Sweden.
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science and Engineering, Solid State Physics.ORCID iD: 0000-0003-2917-8569
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science and Engineering, Solid State Physics.ORCID iD: 0000-0002-0671-435X
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2025 (English)In: ACS Sustainable Chemistry and Engineering, E-ISSN 2168-0485, Vol. 13, no 36, p. 14742-14750Article in journal (Refereed) Published
Abstract [en]

Using seawater can reduce the dependence on freshwater resources to generate hydrogen by electrocatalytic water splitting. However, the stability and activity of hydrogen evolution reaction (HER) electrocatalysts are highly influenced by the pH of seawater. In this regard, the development of the practical application of HER depends on the creation of highly active non-noble metal electrocatalysts. Here, we propose a technique to optimize the electrocatalytic activity and stability of MoO3 by utilizing titanium felt as the substrate. We show an HER overpotential as low as 83 mV at -10 mA cm-2 in neutral pH conditions. The present results show that electrocatalysts based on earth-abundant metals can perform well in saltwater HER, especially at a near-neutral pH (pH similar to 7). In a neutral saltwater electrolyte (0.55 M PBS + 0.5 M NaCl), this electrocatalyst showed stable performance for 250 h at a constant current density of -100 mA cm-2, indicating its promising application in seawater-based hydrogen generation. Compared with noble metals, this electrocatalyst provides a cost-effective option for economic seawater hydrogen generation, promoting the potential of seawater electrolysis.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2025. Vol. 13, no 36, p. 14742-14750
Keywords [en]
non-noble metal, titanium felt, corrosion-resistant, hydrogenevolution reaction, seawater
National Category
Other Chemistry Topics Materials Chemistry
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URN: urn:nbn:se:uu:diva-567696DOI: 10.1021/acssuschemeng.5c02839ISI: 001562288200001Scopus ID: 2-s2.0-105016455895OAI: oai:DiVA.org:uu-567696DiVA, id: diva2:2001476
Funder
Knut and Alice Wallenberg Foundation, 211-0067Swedish Foundation for Strategic Research, 2019-00207Swedish Research Council, KAW 2003.0198Knut and Alice Wallenberg FoundationAvailable from: 2025-09-26 Created: 2025-09-26 Last updated: 2025-09-26Bibliographically approved

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Montero Amenedo, JoséSalazar-Alvarez, Germán

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