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Additive Manufacturing of Biodegradable Magnesium Alloy WE43: Linking Process Parameters to Microstructure and Mechanical Performance
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science and Engineering. (Biomaterial systems)ORCID iD: 0000-0003-3298-5003
2026 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Powder bed fusion – laser beam (PBF-LB) of magnesium (Mg) alloys, particularly WE43 (Mg-4wt%Y-3wt%RE-Zr), offers promising potential for biodegradable medical implants. This thesis investigates the influence of key process parameters in PBF-LB on the microstructure, residual stress, texture, and mechanical properties of alloy WE43 (Mg-4wt%Y-3wt%RE-Zr). This knowledge is intended to support the continued development and implementation of PBF-LB processed WE43 for applications in biodegradable medical implants. The effects of laser power, hatch distance, build size and orientation, as well as laser scan rotation, were systematically investigated. 

Increased energy input through higher laser power promoted equiaxed dendritic grain formation, which enhanced tensile strength. Hatch distance could be optimized to maintain tensile properties even at lower laser powers, and influenced grain size, texture and distribution of secondary phases. Build direction had a large impact on the magnitude of the residual stresses, with larger builds in the vertical direction giving larger stress gradients throughout the sample. Tensile residual stresses were observed at the sample edges, correlating with reduced hardness in those regions compared to the bulk.

Horizontally built specimens showed approximately 40% higher tensile strength (215 MPa vs 150 MPa) and about 20% higher elastic modulus (44 GPa vs 37 GPa) than vertically built ones, primarily due to the development of a strong basal texture along the build direction. This anisotropy implies that part orientation during PBF-LB has a significant impact on performance in service. It was demonstrated that laser scan rotation significantly influences the crystallographic texture, which has the potential to affect the mechanical response of the printed parts. Rotations of 67° and 90° maintain high densification and mechanical integrity while modifying texture. Rotations of 60° and 120° further demonstrate texture control, and a segmented chessboard strategy enhances compressive strength despite weaker texture, due to favourable pore distribution and dendritic grain formation. Conversely, limiting scan rotation to 0° or 180° results in poor densification (<99% relative density), compromising structural integrity. Together, the work included in the thesis provides a comprehensive foundation for PBF-LB considerations to achieve desirable microstructural and mechanical outcomes in WE43, supporting its potential use in biomedical applications.

Place, publisher, year, edition, pages
Uppsala: Acta Universitatis Upsaliensis, 2026. , p. 79
Series
Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology, ISSN 1651-6214 ; 2601
Keywords [en]
Powder bed fusion - laser beam, additive manufacturing, magnesium, WE43, microstructure
National Category
Metallurgy and Metallic Materials
Research subject
Engineering Science with specialization in Biomedical Engineering
Identifiers
URN: urn:nbn:se:uu:diva-569726ISBN: 978-91-513-2633-7 (print)OAI: oai:DiVA.org:uu-569726DiVA, id: diva2:2006697
Public defence
2026-03-06, Häggsalen, Ångströmlaboratoriet, Lägerhyddsvägen 1, Uppsala, 09:15 (English)
Opponent
Supervisors
Available from: 2026-01-29 Created: 2025-10-15 Last updated: 2026-03-04Bibliographically approved
List of papers
1. Higher Laser power improves strength but reduces corrosion resistance of Mg WE43 processed by powder bed fusion
Open this publication in new window or tab >>Higher Laser power improves strength but reduces corrosion resistance of Mg WE43 processed by powder bed fusion
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2024 (English)In: Materials Today Communications, ISSN 2352-4928, Vol. 39, article id 108979Article in journal (Refereed) Published
Abstract [en]

Powder bed fusion – laser beam (PBF-LB) of Mg alloys provides new possibilities for the production of complex structures with optimized designs, both for weight reduction in aerospace applications, as well as for patient-specific implants in orthopedic applications. However, even though numerous studies have been carried out on the topic, the influence of the individual PBF-LB process parameters on the microstructure and resulting material properties of Mg alloys remains ambiguous. Thus, this study aims to investigate the influence of laser power on the surface roughness, microstructure and resulting key material properties, namely corrosion resistance and mechanical performance. Samples were produced by PBF-LB from gas atomized Mg-4%Y-3%Nd-0.5%Zr (WE43) alloy powder, using three different laser powers: 60 W, 80 W, and 90 W. Contrary to expectation, the 90 W samples exhibited the highest degradation rate, while 60 W samples had the lowest, despite the latter having highest surface roughness and large internal pores. The higher degradation rate for the 90 W samples was instead found to stem from the near-surface microstructure. The higher energy input and subsequently reduced grain size, resulted in an increased amount of second phase precipitates than for the 60 W samples, thereby increasing the tendency for pitting via microgalvanic corrosion. For the tensile strength and elongation at break, the opposite trend was observed. Here, a reduction in grain size and an increase in precipitates for the 90 W samples were found to be beneficial. In conclusion, a definite influence of laser power on the formation of microstructure was observed, ultimately impacting the resulting corrosion and tensile properties of WE43. Future work should investigate the influence of other PBF-LB process parameters, with the aim of establishing an optimum balance between corrosion resistance and mechanical properties.

Place, publisher, year, edition, pages
Elsevier, 2024
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:uu:diva-508530 (URN)10.1016/j.mtcomm.2024.108979 (DOI)001237794100001 ()
Funder
Vinnova, 2019-05259Swedish Foundation for Strategic Research, FID17-0028Swedish Foundation for Strategic Research, GSn15 – 0008Vinnova, 2019-00029Swedish Research Council, 2021-04708
Available from: 2023-08-03 Created: 2023-08-03 Last updated: 2025-10-15Bibliographically approved
2. Laser hatch distance can tune corrosion behaviour and mechanical properties while maintaining in vitro biocompatibility of additively manufactured Mg alloy WE43
Open this publication in new window or tab >>Laser hatch distance can tune corrosion behaviour and mechanical properties while maintaining in vitro biocompatibility of additively manufactured Mg alloy WE43
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(English)Manuscript (preprint) (Other academic)
National Category
Medical Materials
Identifiers
urn:nbn:se:uu:diva-569653 (URN)
Available from: 2025-10-15 Created: 2025-10-15 Last updated: 2025-10-15
3. On the relationship between process parameters and residual stress in large WE43 builds produced by PBF-LB
Open this publication in new window or tab >>On the relationship between process parameters and residual stress in large WE43 builds produced by PBF-LB
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(English)Manuscript (preprint) (Other academic)
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:uu:diva-569446 (URN)
Available from: 2025-10-14 Created: 2025-10-14 Last updated: 2025-10-15
4. Leveraging laser powder bed fusion to alter texture and mechanical properties of magnesium alloy WE43
Open this publication in new window or tab >>Leveraging laser powder bed fusion to alter texture and mechanical properties of magnesium alloy WE43
2025 (English)In: Materials & design, ISSN 0264-1275, E-ISSN 1873-4197, Vol. 256, article id 114299Article in journal (Refereed) Published
Abstract [en]

The present work explored the potential of customizing the final part texture and mechanical properties of a biodegradable magnesium alloy (WE43, composition Mg-4 wt%Y-3 wt%Nd-0.5 wt%Zr) manufactured by laser beam powder bed fusion (PBF-LB). This was done by printing samples using two sets of laser scan strategies (670 and 900 rotation between consecutively scanned layers) and build directions (horizontal and vertically printed samples). Samples were characterized for density and microstructure, followed by in-depth texture analysis using both lab-based techniques and neutron diffraction measurements. The mechanical performance was evaluated through tensile testing. The findings in this work show that strong basal texture was generated in the build direction. This allowed for altering the mechanical strength of WE43, whereby horizontally built samples showed increased strength and Young's modulus under tensile loading in a direction normal to the basal texture. Laser scan strategy influences the overall texture, however with limited effect on the resulting mechanical properties for the two scan strategies under study. This study demonstrates the importance of sample design and build strategy for the resulting texture and final material properties.

Place, publisher, year, edition, pages
Elsevier, 2025
Keywords
Laser beam powder bed fusion, WE43, Magnesium, Texture, Mechanical properties
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:uu:diva-563636 (URN)10.1016/j.matdes.2025.114299 (DOI)001522100600001 ()2-s2.0-105008968519 (Scopus ID)
Funder
Swedish Foundation for Strategic ResearchVinnova, 2019-00029Swedish Research Council, 2022-03069
Available from: 2025-07-14 Created: 2025-07-14 Last updated: 2025-10-15Bibliographically approved
5. The role of laser scan rotation in additive manufacturing of Mg-RE alloy WE43
Open this publication in new window or tab >>The role of laser scan rotation in additive manufacturing of Mg-RE alloy WE43
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(English)Manuscript (preprint) (Other academic)
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:uu:diva-569652 (URN)
Available from: 2025-10-15 Created: 2025-10-15 Last updated: 2025-10-15

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