Logo: to the web site of Uppsala University

uu.sePublications from Uppsala University
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Exciton many-body interactions and charge transfer in CsPbBr3/graphene derivatives
Indian Inst Sci Educ & Res Bhopal, Dept Phys, Bhopal 462066, India..
Indian Inst Sci Educ & Res Bhopal, Dept Phys, Bhopal 462066, India..
Indian Inst Sci Educ & Res Bhopal, Dept Phys, Bhopal 462066, India..
Indian Inst Sci Educ & Res Bhopal, Dept Phys, Bhopal 462066, India..
Show others and affiliations
2023 (English)In: Physical Review B, ISSN 2469-9950, E-ISSN 2469-9969, Vol. 108, no 15, article id 155417Article in journal (Refereed) Published
Abstract [en]

Charge separation and many-body interactions at the interface of the light-absorbing semiconductor and contact layer are of crucial importance to the photophysical properties and optoelectronic device performance. Here, we report the exciton many-body interactions and charge transfer dynamics at the interface of metal halide perovskite nanocrystals and graphene derivatives [graphene oxide (GO) and reduced GO (RGO)] using ultrafast transient absorption (TA) and time-resolved photoluminescence (PL) measurements. At the early timescales, the TA spectra of CsPbBr3/GO and CsPbBr3/RGO show an asymmetric derivative feature originating from the exciton many-body interactions. The band gap renormalization and binding energies of exciton and biexciton of CsPbBr3 nanocrystals are significantly reduced in CsPbBr3/GO(RGO) due to the charge transfer and change in the dielectric environment, respectively. More specifically, the exciton (biexciton) binding energy of CsPbBr3 nanocrystals, originally 38 +/- 2 (34 +/- 1) meV, decreases to 27 +/- 1 (22 +/- 1) meV in CsPbBr3/RGO and 17 +/- 1 (15 +/- 1) meV in CsPbBr3/GO. Furthermore, we observe a reduction in the Auger recombination rate and exciton PL quenching in CsPbBr3/GO and CsPbBr3/RGO, corroborating the charge transfer mechanism. Our systematic studies successfully describe photoexcited charge transfer from CsPbBr3 nanocrystals to GO (RGO) in 7.0 +/- 0.4 (4.2 +/- 0.1) ps, which is one order of magnitude faster than the charge transfer for other acceptor materials such as metal oxide, fullerene, anthraquinone, 1-aminopyrene, and phenothiazine. Our results offer insights and guidance for perovskite-based high-performance optoelectronic devices.

Place, publisher, year, edition, pages
American Physical Society, 2023. Vol. 108, no 15, article id 155417
National Category
Condensed Matter Physics Atom and Molecular Physics and Optics Materials Chemistry Physical Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-518349DOI: 10.1103/PhysRevB.108.155417ISI: 001087449300001OAI: oai:DiVA.org:uu-518349DiVA, id: diva2:1821089
Available from: 2023-12-19 Created: 2023-12-19 Last updated: 2024-01-12Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full text

Authority records

Karmakar, Debjani

Search in DiVA

By author/editor
Karmakar, Debjani
By organisation
Materials Theory
In the same journal
Physical Review B
Condensed Matter PhysicsAtom and Molecular Physics and OpticsMaterials ChemistryPhysical Chemistry

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 96 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf