Exciton many-body interactions and charge transfer in CsPbBr3/graphene derivativesShow others and affiliations
2023 (English)In: Physical Review B, ISSN 2469-9950, E-ISSN 2469-9969, Vol. 108, no 15, article id 155417Article in journal (Refereed) Published
Abstract [en]
Charge separation and many-body interactions at the interface of the light-absorbing semiconductor and contact layer are of crucial importance to the photophysical properties and optoelectronic device performance. Here, we report the exciton many-body interactions and charge transfer dynamics at the interface of metal halide perovskite nanocrystals and graphene derivatives [graphene oxide (GO) and reduced GO (RGO)] using ultrafast transient absorption (TA) and time-resolved photoluminescence (PL) measurements. At the early timescales, the TA spectra of CsPbBr3/GO and CsPbBr3/RGO show an asymmetric derivative feature originating from the exciton many-body interactions. The band gap renormalization and binding energies of exciton and biexciton of CsPbBr3 nanocrystals are significantly reduced in CsPbBr3/GO(RGO) due to the charge transfer and change in the dielectric environment, respectively. More specifically, the exciton (biexciton) binding energy of CsPbBr3 nanocrystals, originally 38 +/- 2 (34 +/- 1) meV, decreases to 27 +/- 1 (22 +/- 1) meV in CsPbBr3/RGO and 17 +/- 1 (15 +/- 1) meV in CsPbBr3/GO. Furthermore, we observe a reduction in the Auger recombination rate and exciton PL quenching in CsPbBr3/GO and CsPbBr3/RGO, corroborating the charge transfer mechanism. Our systematic studies successfully describe photoexcited charge transfer from CsPbBr3 nanocrystals to GO (RGO) in 7.0 +/- 0.4 (4.2 +/- 0.1) ps, which is one order of magnitude faster than the charge transfer for other acceptor materials such as metal oxide, fullerene, anthraquinone, 1-aminopyrene, and phenothiazine. Our results offer insights and guidance for perovskite-based high-performance optoelectronic devices.
Place, publisher, year, edition, pages
American Physical Society, 2023. Vol. 108, no 15, article id 155417
National Category
Condensed Matter Physics Atom and Molecular Physics and Optics Materials Chemistry Physical Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-518349DOI: 10.1103/PhysRevB.108.155417ISI: 001087449300001OAI: oai:DiVA.org:uu-518349DiVA, id: diva2:1821089
2023-12-192023-12-192024-01-12Bibliographically approved