Magnetoelastic and giant frequency dispersion in MnCo2O4 spinel: Quenched Jahn-Teller distortion by Cr and Fe substitutionShow others and affiliations
2026 (English)In: Journal of Alloys and Compounds, ISSN 0925-8388, E-ISSN 1873-4669, Vol. 1062, article id 187534Article in journal (Refereed) Published
Abstract [en]
We report magnetoelastic (0.46%) features and giant frequency dispersion (Δω ∼ 317 rad/s, ΔT ∼ 34 K) of ac-magnetic susceptibility (χac) (ω,T)) at two distinct temperatures (TP1-ac = 144 K and TP2-ac = 211 K) in Cr and Fe co-substituted MnCo2O4 cubic (Fd<over bar>3m) spinel forming the composition Cr0.2Mn0.8Fe0.4Co1.6O4. A detailed temperature dependence of neutron and synchrotron x-ray diffraction studies reveal anomalous changes in the lattice parameter across ferrimagnetic (FiM) ordering (TC = 260 K), as well as at two additional transitions TS1 ∼ 114 K and TS2 similar to 173 K. Competing antiferromagnetic exchange interactions among the cations (JAA/kB = 23.2 K, JBB/kB = 9.15 K, and JAB/kB = 25.25 K) are responsible for the giant frequency dispersion observed in χac(ω, T), while ruling out the presence of a conventional spin-glass state below TC. The Kubelka Munk analysis of the optical absorbance data is used to find the optical band gap of 1.16 eV (Eg). The optical absorption spectrum reveals well defined d-d transitions attributed to the charge transfer in this investigated system. Such substantial red-shift compared to the pristine p-type semiconducting Co3O4 together with the FiM behavior of this compound may open a constructive approach for applications in magneto electronics.
Place, publisher, year, edition, pages
Elsevier, 2026. Vol. 1062, article id 187534
Keywords [en]
Ferrimagnetism, Spinels, Neutron diffraction, Jahn-Teller distortion, Magnetoelastic features, Frequency dispersion
National Category
Condensed Matter Physics
Identifiers
URN: urn:nbn:se:uu:diva-584737DOI: 10.1016/j.jallcom.2026.187534ISI: 001735074900001Scopus ID: 2-s2.0-105034144110OAI: oai:DiVA.org:uu-584737DiVA, id: diva2:2055114
Funder
Swedish Research Council, 2021-036752026-04-232026-04-232026-04-23Bibliographically approved